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What is the chemical composition of UNS S32750?

Views: 0     Author: Site Editor     Publish Time: 2025-02-13      Origin: Site

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Introduction


UNS S32750, commonly known as Super Duplex Stainless Steel 2507, is a highly alloyed stainless steel designed for applications requiring exceptional strength and corrosion resistance. This material combines the desirable aspects of both austenitic and ferritic stainless steels, offering a balance of excellent mechanical properties and superior resistance to stress corrosion cracking. Understanding the 2507-UNS S32750 is essential for industries operating in harsh environments where material performance is critical.



Chemical Composition of UNS S32750


The chemical composition of UNS S32750 is meticulously engineered to enhance its performance in aggressive environments. The alloying elements play a pivotal role in determining its mechanical properties and corrosion resistance.



Primary Alloying Elements


UNS S32750 is composed of approximately 25% chromium (Cr), 7% nickel (Ni), 4% molybdenum (Mo), and 0.3% nitrogen (N). The high chromium content provides excellent resistance to chloride-induced stress corrosion cracking, while nickel enhances overall corrosion resistance and toughness. Molybdenum significantly improves resistance to pitting and crevice corrosion, and nitrogen serves to increase strength and resistance to pitting.



Detailed Composition Breakdown


The typical chemical composition of UNS S32750 is as follows:



  • Chromium (Cr): 24.0-26.0%

  • Nickel (Ni): 6.0-8.0%

  • Molybdenum (Mo): 3.0-5.0%

  • Nitrogen (N): 0.24-0.32%

  • Manganese (Mn): 1.20% max

  • Silicon (Si): 0.80% max

  • Phosphorus (P): 0.035% max

  • Sulfur (S): 0.020% max

  • Carbon (C): 0.030% max

  • Iron (Fe): Balance


These elements collectively contribute to the alloy's duplex microstructure, characterized by approximately equal proportions of ferrite and austenite phases.



Microstructural Characteristics


The duplex microstructure of UNS S32750 results in a combination of austenitic and ferritic grains. This structure is crucial for achieving the superior mechanical and corrosion-resistant properties that distinguish this alloy from standard stainless steels.



Duplex Structure Benefits


The dual-phase microstructure imparts high strength and resistance to chloride stress corrosion cracking, a common failure mode in stainless steels. The ferritic phase provides resistance to stress corrosion cracking, while the austenitic phase contributes to toughness and ductility.



Mechanical Properties of UNS S32750


UNS S32750 exhibits exceptional mechanical properties, making it suitable for demanding structural applications.



Strength and Toughness


The alloy has a high yield strength, typically around 550 MPa, and tensile strength exceeding 800 MPa. Its elongation at break is approximately 15%, indicating good ductility. The combination of high strength and toughness allows for thinner sections to be used in design, reducing overall weight without compromising structural integrity.



Impact Resistance


UNS S32750 maintains excellent impact toughness, even at sub-zero temperatures. This property is critical in applications where materials are exposed to varying temperatures and mechanical stresses.



Corrosion Resistance of UNS S32750


One of the most significant advantages of UNS S32750 is its superior corrosion resistance in harsh environments.



Resistance to Pitting and Crevice Corrosion


The high chromium, molybdenum, and nitrogen contents provide outstanding resistance to pitting and crevice corrosion in chloride-containing environments. Its Pitting Resistance Equivalent Number (PREN) exceeds 40, signifying excellent performance in seawater and other aggressive chloride solutions.



Stress Corrosion Cracking Resistance


UNS S32750 exhibits exceptional resistance to chloride stress corrosion cracking, a common issue in austenitic stainless steels. This resistance extends the material's life span in environments where high tensile stresses and chlorides are present.



General Corrosion Resistance


The alloy is also resistant to general corrosion in acidic environments. It performs well in solutions containing sulphuric and phosphoric acids, making it suitable for chemical processing industries.



Applications of UNS S32750


Due to its exceptional properties, UNS S32750 is employed in various industries where material performance is paramount.



Oil and Gas Industry


In the oil and gas sector, UNS S32750 is used for tubing, piping, and structural components exposed to harsh subsea environments. Its resistance to corrosion and high mechanical strength make it ideal for offshore platforms and processing equipment.



Chemical Processing


The alloy's ability to withstand acidic environments makes it suitable for chemical processing equipment such as heat exchangers, pressure vessels, and piping systems handling aggressive chemicals.



Desalination Plants


UNS S32750 is commonly used in desalination facilities due to its excellent resistance to chlorides and seawater corrosion, ensuring longevity and reliability of components like evaporators and pumps.



Comparison with Other Duplex Stainless Steels


Understanding how UNS S32750 compares with other duplex stainless steels is crucial for material selection.



UNS S32205 vs. UNS S32750


UNS S32205 (2205 duplex) is another widely used duplex stainless steel. While both alloys offer good corrosion resistance and strength, UNS S32750 has higher alloy content, leading to better performance especially in aggressive environments. The higher molybdenum and chromium content in UNS S32750 enhances its pitting resistance.



Cost Considerations


Due to its higher alloying elements, UNS S32750 is generally more expensive than lower alloyed duplex steels. However, its extended service life and reduced maintenance can offset initial costs in long-term applications.



Fabrication and Welding


Proper fabrication techniques are essential to maintain the properties of UNS S32750 during processing.



Welding Practices


Welding UNS S32750 requires careful control of heat input and interpass temperatures to prevent detrimental phase formations. Filler metals matching the alloy composition are used to ensure weld integrity and corrosion resistance are maintained.



Heat Treatment


Post-weld heat treatment is typically not required for UNS S32750. However, solution annealing may be performed to restore a balanced duplex microstructure after significant cold working or high-temperature exposure.



Case Studies and Performance Data


Several studies and applications have demonstrated the superior performance of UNS S32750 in challenging environments.



Offshore Platform Performance


In offshore oil platforms, components made from UNS S32750 have shown remarkable resistance to seawater corrosion over extended periods. Studies indicate a significant reduction in maintenance costs due to the material's durability.



Chemical Plant Reliability


Chemical processing plants utilizing UNS S32750 for heat exchangers have reported increased operational reliability. The alloy's resistance to acidic corrosion minimizes unexpected shutdowns and extends equipment life.



Standards and Specifications


UNS S32750 conforms to several international standards, ensuring its suitability for global applications.



ASTM Standards


The alloy is specified under various ASTM standards, such as ASTM A240 for plate, sheet, and strip; ASTM A789 and A790 for seamless and welded pipe; and ASTM A182 for forged fittings.



ISO and EN Standards


UNS S32750 corresponds to EN 1.4410 and is recognized under ISO standards for its consistent quality and performance. These standards facilitate its acceptance and use in international projects.



Environmental Impact and Sustainability


Selecting materials with a lower environmental impact is increasingly important in modern industries.



Longevity and Lifecycle


UNS S32750's durability reduces the need for frequent replacements, thereby decreasing material consumption and waste over the life of a project. Its extended service life contributes to sustainability goals.



Recyclability


The alloy is fully recyclable, aligning with circular economy principles. Recycling stainless steel conserves raw materials and reduces energy consumption compared to producing new alloys from virgin resources.



Conclusion


UNS S32750, or Super Duplex Stainless Steel 2507, stands out as a material of choice for applications demanding high strength and superior corrosion resistance. Its carefully balanced chemical composition results in a duplex microstructure that offers the best of both austenitic and ferritic stainless steels. Industries ranging from oil and gas to chemical processing benefit from its reliability and performance in extreme conditions. Understanding the properties and applications of 2507-UNS S32750 enables engineers and material specialists to make informed decisions that enhance safety, efficiency, and sustainability in their projects.

Jiangsu HYT International

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